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So when I try to link my village on my iPad 1 to my new iPhone 5S it says that my village is not in sync with Game Center but I know it is. Then I saw that the link the device option doesn't support iOS 5 (which my iPad 1 is on.) Thanks for reading :)
Not entirely sure what you are trying to say there.
The link feature is for Apple to Android linking, or vice versa.
To play on another Apple device you only need to log in to the Game Center account that the village is linked to and you will get a pop-up notification in-game asking you if you want to load that village.